back when i was a huge weeb, i shipped kagome/kikyo from inuyasha. it helped that they were so different in personality and often at odds for one reason or another.

also, rem/misa from death note because i considered rem to be as close to a woman shinigami as you could really get. it seemed obvious that she developed feelings for misa much like a previous shinigami did, since she was willing to die for her.

ntm michuru/haruka from sailor moon and zakuro/minto from tokyo mew mew and anthy/utena from revolutionary girl utena